How to extract S-parameters (S11, S21, S21, and S22) from passive network?

I suppose that Mike @Engelhardt was referring to the Winslow Impedance Probe, which is not quite the same as the .net directive, but can also be pretty useful. For simulating the S-parameters of a circuit directly, I would also recommend the setup shown in Figure 25 of https://designers-guide.org/forum/Attachments/CreateS-ParameterSUBCKTinPSpice.pdf.